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**IC7101 THERMODYNAMICS FOR IC ENGINEERING L T P C 3 1 0 4**
__AIM:__
To enrich the knowledge of students in thermodynamics

__OBJECTIVES:__
- To achieve an understanding of basic principle and scope of thermodynamics.
- To predict the availability and irreversibility associated with the thermodynamic processes.
- To analyse the properties of ideal and real gas mixtures and to understand the basic concepts of thermal systems

UNIT I THERMODYNAMIC PROPERTY RELATIONS 9

Thermodynamic Potentials, Maxwell relations, Generalised relations for changes in Entropy, Internal

Energy and Enthalpy, Generalised Relations for Cp and Cv, Clausius Clayperon Equation, Joule- Thomson Coefficient, Bridgeman Tables for Thermodynamic Relations.

UNIT II REAL GAS BEHAVIOUR AND MULTI-COMPONENT SYSTEMS 9

Equations of State (mention three equations), Fugacity, Compressibility, Principle of Corresponding

States, Use of generalised charts for enthalpy and entropy departure, fugacity coefficient, Lee-Kesler

generalised three parameter tables. Fundamental property relations for systems of variable

composition, partial molar properties, Real gas mixtures, Ideal solution of real gases and liquids,

Equilibrium in multi-phase systems, Gibbs phase rule for non-reactive components.

UNIT III CHEMICAL AVAILABILITY 9

Introduction, Reversible work, Availability, Irreversibility and Second-Law Efficiency for a closed

System and Steady-State Control Volume. Availability Analysis of Simple Cycles. Chemical

availability, Environmental state, Air-conditioning processes. Fuel Chemical availability, availability

analysis of chemical processes – steam power plant, combustion and heat transfer losses, preheated

inlet air, problems.

UNIT IV FUEL – AIR CYCLES AND THEIR ANALYSIS 9

Ideal gas laws and properties of Mixtures, Combustion Stoichiometry, Application of First Law of

Thermodynamics – Heat of Reaction – Enthalpy of Formation – Adiabatic flame temperature. Second

law of Thermodynamics applied to combustion – entropy, maximum work and efficiency

UNIT V THERMO CHEMISTRY 9

Chemical equilibrium: - Equilibrium combustion products. Dynamic properties of working fluids: - Unburned mixture – Low temperature combustion products – High temperature combustion products,

problems.

T=15, TOTAL: 60 PERIODS

__OUTCOME: __
On successful completion of this course the student will be able to apply the law of

thermodynamics to thermal systems.

__REFERENCES:__
1. Kenneth Wark., J. R, Advanced Thermodynamics For Engineers, McGraw-Hill Inc., 1995.

2. Yunus A. Cengel and Michael A . Boles, Thermodynamics, McGraw-Hill Inc., 2006.

3. B.P. Pundir, I.C. engine combustion and emissions.

4. Bejan, A., Advanced Engineering Thermodynamics, John Wiley and Sons, 1988.

5. Holman,J.P., Thermodynamics, Fourth Edition, McGraw-Hill Inc., 1988

6. Smith, J.M. and Van Ness., H.C., Introduction to Chemical Engineering Thermodynamics, Fourth

Edition, McGraw-Hill Inc., 1987.6

7. Sonntag, R.E., and Van Wylen, G, Introduction to Thermodynamics, Classical and Statistical Third

Edition, , John Wiley and Sons, 1991

8. Sears, F.W. and Salinger G.I., Thermodynamics, Kinetic Theory and Statistical Thermodynamics,

Third Edition, Narosa Publishing House, New Delhi, 1993.

9. DeHotf, R.T., Thermodynamics in Materials Science, McGraw-Hill Inc., 1993.

10. Rao, Y.V.C., Postulational and Statistical Thermodynamics, Allied Publisher Limited, New Delhi,

1994